Per B. Zetterlund
Ph.D.
Jannuary. 27, 1968
Associate Professor
CX-6
| Academic Career | 1994 MSc, Royal Institute of Technology (Stockholm, Sweden) 1998 Ph.D, University of Leeds (Leeds, United Kingdom) |
|---|---|
| Professional Career | 1998 – 1999 Postdoctoral Research Fellow, Griffith University (Brisbane, Australia), School of Science. 1999 – 2003 Assistant Professor, Osaka City University (Japan), Department of Applied and Bioapplied Chemistry. 2003 - 2005 Assistant Professor, Graduate School of Science and Technology, Kobe University. 2006- Associate Professor, Faculty of Engineering, Kobe University 2007- present Associate Professor, Graduate School of Engineering, Kobe University |
| Field of Instruction and Research | Free radical polymerization (kinetic/synthetic aspects) Simulation of free radical polymerization processes |
| Research Activities |
Free radical polymerization (kinetic/synthetic aspects) Initiation processes in free radical polymerization Nitroxide-mediated controlled/living free radical polymerization Simulation of free radical polymerization processes |
| Main Publications | 74. Improved Control in Nitroxide-Mediated Radical Polymerization using Supercritical Carbon Dioxide, F. Aldabbagh, P. B. Zetterlund, M. Okubo, Macromolecules, in press. 73. Quantification of Spontaneous Initiation in Radical Polymerization of Styrene in Aqueous Miniemulsion at High Temperature, Md. N. Alam, P. B. Zetterlund, M. Okubo, Polymer, in press. 72. Nitroxide-Mediated Controlled/Living Radical Copolymerizations with Macromonomers, J. Ryan, F. Aldabbagh, P. B. Zetterlund, B. Yamada, React. Funct. Polym. in press. 71. Use of Fluorescence-Labelled Macroinitiator to Investigate Nucleation Mechanism in Nitroxide-Mediated Crosslinking Polymerization in Aqueous Miniemulsion, P. B. Zetterlund, Md. N. Alam, M. Okubo, Polym. J., 2008, 40, 2-3. 70. Nitroxide-Mediated Radical Polymerization in Microemulsion, J. Wakamatsu, M. Kawasaki, P. B. Zetterlund, M. Okubo, Macromol. Rapid Commun. 2007, 28, 2346-2353. 69. Atom Transfer Radical Polymerization of iso-Butyl Methacrylate in Microemulsion with Cationic and Nonionic Emulsifiers, Y. Kagawa, M. Kawasaki, P. B. Zetterlund, H. Minami, M. Okubo, Macromol. Rapid Commun. 2007, 28, 2354-2360. 68. Mechanistic Investigation of Particle Size Effects in TEMPO-Mediated Radical Polymerization of Styrene in Aqueous Miniemulsion, P. B. Zetterlund, T. Nakamura, M. Okubo, Macromolecules, 2007, 40, 8663-8672. 67. Determination of the Propagation Rate Coefficient of Vinyl Pivalate based on EPR Quantification of Propagating Radical Concentration, N. Kubota, A. Kajiwara, P. B. Zetterlund, M. Kamachi, J. Treurnicht, M. P. Tonge, R. G. Gilbert, B. Yamada, Macromol. Chem. Phys. 2007, 208, 2403-2411. 66. Nitroxide-Mediated Radical Polymerization in Miniemulsion: Bimolecular Termination in Monomer-Free Model Systems, Md. N. Alam, P. B. Zetterlund, M. Okubo, J. Polym. Sci.; Part A: Polym. Chem. 2007, 45, 4995-5004. 65. Nitroxide-Mediated Radical Precipitation Polymerization of Styrene in Supercritical Carbon Dioxide, R. McHale, F. Aldabbagh, P. B. Zetterlund, M. Okubo, Macromol. Chem. Phys. 2007, 208, 1813-1822. 64. Mechanical Properties of Cross-linked Polymer Particles Prepared by Nitroxide-Mediated Radical Polymerization in Aqueous Micro-Suspension, Takuya Tanaka, Toyoko Suzuki, Yuichi Saka, Per B. Zetterlund, Masayoshi Okubo, Polymer, 2007, 48, 3836-3843. 63. Atom Transfer Radical Polymerization in Miniemulsion: Partitioning Effects of Cu(I) and Cu(II) on Polymerization Rate, Livingness, and Molecular Weight Distribution, Y. Kagawa, P. B. Zetterlund, H. Minami, M. Okubo, Macromolecules 2007, 40, 3062-3069. 62. The Role of Excess Nitroxide in the SG1 (N-tert-butyl-N-[1-diethylphosphono-(2,2-dimethylpropyl)] nitroxide)-Mediated Polymerization of Methyl Methacrylate, R. McHale, F. Aldabbagh, P. B. Zetterlund, J. Polym. Sci.; Part A: Polym. Chem. 2007, 45, 2194-2203. 61. Compartmentalization in TEMPO-mediated Radical Polymerization in Dispersed Systems: Effects of Macroinitiator Concentration, P. B. Zetterlund, M. Okubo, Macromol. Theory Simul. 2007, 16, 221-226. 60. Gel Formation and Primary Chain Lengths in Nitroxide-mediated Radical Copolymerization of Styrene and Divinylbenzene in Miniemulsion, Y. Saka, P. B. Zetterlund, M. Okubo, Polymer, 2007, 48, 1229-1236. 59. Compartmentalization in Nitroxide-Mediated Radical Polymerization in Dispersed Systems, P. B. Zetterlund, M. Okubo, Macromolecules, 2006, 39, 8959-8967. 58. Particle Size Effects in TEMPO-Mediated Radical Polymerization of Styrene in Aqueous Miniemulsion, T. Nakamura, P. B. Zetterlund, M. Okubo, Macromol. Rapid Commun. 2006, 27, 2014-2018. 57. Utility of Propenyl Groups in Free Radical Polymerization: Effects of Steric Hindrance on Formation and Reaction Behavior as Versatile Intermediates, B. Yamada, P. B. Zetterlund, E. Sato, Prog. Polym. Sci., 2006, 31, 835-877. 56. Nitroxide-Çlediated Radical Polymerization of Styrene: Experimental Evidence of Chain Transfer to Monomer, P. B. Zetterlund, Y. Saka, R. McHale, T. Nakamura, F. Aldabbagh, M. Okubo, Polymer 2006, 47, 7900-7908. 55. Network Formation in Nitroxide-Mediated Radical Copolymerization of Styrene and Divinylbenzene in Miniemulsion, Md. N. Alam, P. B. Zetterlund, M. Okubo, Macromol. Chem. Phys. 2006, 207, 1732-1741. 54. Compartmentalization in Atom Transfer Radical Polymerization (ATRP) in Dispersed Systems, Y. Kagawa, P. B. Zetterlund, H. Minami, M. Okubo, Macromol. Theory Simul. 2006, 15, 608-613. 53. Nitroxide-Mediated Radical Dispersion Polymerization of Styrene in Supercritical Carbon Dioxide using a Poly(dimethylsiloxane-b-methyl methacrylate) Stabilizer, R. McHale, F. Aldabbagh, P. B. Zetterlund, H. Minami, M. Okubo, Macromolecules 2006, 39, 6853-6860. 52. Copolymerization of Eight-Membered Ring-Opening Allylic Sulfide Lactone and Disulfide Monomers with Methyl Methacrylate and Styrene, M. Phelan, F. Aldabbagh, P. B. Zetterlund, B. Yamada, Eur. Polym. J. 2006, 42, 2475-2485. 51. Nitroxide-Mediated Radical Dispersion Polymerization of Styrene in Supercritical Carbon Dioxide using a Poly(dimethylsiloxane-b-styrene) Alkoxyamine as Initiator and Stabilizer, R. McHale, F. Aldabbagh, P. B. Zetterlund, M. Okubo, Macromol. Rapid Commun 2006, 27, 1465-1471. 50. Effects of Laplace Pressure on Propagation and Termination in Aqueous Heterogeneous Free Radical Polymerization, P. B. Zetterlund, M. Okubo, Macromol. Theory Simul 2006, 15, 40-45. 49. Mechanism and kinetics of the free radical ring-opening polymerization of cyclic allylic sulfide lactones, M. Phelan, F. Aldabbagh, P. B. Zetterlund, B. Yamada, Polymer 2005, 46, 12046-12056. 48. First nitroxide-mediated free radical dispersion polymerizations of styrene in supercritical carbon dioxide, J. Ryan, F. Aldabbagh, P. B. Zetterlund, M. Okubo, Polymer 2005, 46, 9769-9777. 47. Nitroxide-Mediated Radical Polymerization in Miniemulsion at Stationary State: Rationale for Independence of Polymerization Rate on Nitroxide Partitioning Using Oil-phase Initiation, P. B. Zetterlund, M. Okubo, Macromol. Theory Simul. 2005, 14, 415-420. 46. Nitroxide-Mediated Controlled/Living Free Radical Copolymerization of Styrene and Divinylbenzene in Aqueous Miniemulsion, P. B. Zetterlund, Md. N. Alam, H. Minami, M. Okubo, Macromol. Rapid Commun. 2005, 26, 955-960. 45. Critically Evaluated Termination Rate Coefficients for Free-Radical Polymerization, 2. Experimental Methods, C. Barner-Kowollik, M. Buback, M. Egorov, T. Fukuda, A. Goto, O. F. Olaj, G. T. Russell, P. Vana, B. Yamada, P. B. Zetterlund, Prog. Polym. Sci., 2005, 30, 605-643. 44. Mechanism and Kinetics of the Free Radical Ring-Opening Polymerization of Eight-Membered Cyclic Allylic Disulfide Monomers, M. Phelan, F. Aldabbagh, P. B. Zetterlund, B. Yamada, Macromolecules 2005, 38, 2143-2147. 43. Instantaneous Copolymer Composition in High Conversion Copolymerization of Acrylonitrile and Methyl Acrylate Assessed by in situ 13C-NMR Measurements of Individual Monomer Reaction Rates, P. B. Zetterlund, M. Takenaka, A. F. Johnson, Macromolecules 2005, 38, 2173-2179. 42. Addition-Fragmentation Chain Transfer to Polymer in the Free Radical Ring-Opening Polymerization of an Eight-membered Cyclic Allylic Sulfide Monomer, M. Phelan, F. Aldabbagh, P. B. Zetterlund, B. Yamada, Macromol Theory Simul. 2005, 14, 109-116. 41. Chain Transfer and Efficiency of End Group Introduction in Free Radical Polymerization of Methyl Methacrylate in the Presence of Poly(methyl methacrylate) Macromonomer, K. Miyake, P. B. Zetterlund, B. Yamada, Macromolecular Rapid Communications 2004, 25, 1905. 40. Influence of mid-chain radicals on acrylate free radical polymerization: Effect of ester alkyl group assessed via comparison of tert-butyl and 2-ethylhexyl acrylate, E. Sato, T. Emoto, P. B. Zetterlund., B. Yamada, Macromol. Chem. Phys., 2004, 205, 1829. 39. Macromonomer Synthesis Using a-(2-Methyl-2-phenylpropyl)acrylates as Addition-Fragmentation Chain Transfer Agents Expelling the Cumyl Radical, E. Sato, P. B. Zetterlund, B. Yamada, J. Polym. Sci.; Part A: Polym. Chem., 2004, 42, 6021. 38. First Nitroxide-Mediated Controlled/Living Free Radical Polymerization in an Ionic Liquid, J. Ryan, F. Aldabbagh, P. B. Zetterlund, B. Yamada, Macromol. Rapid Commun. 2004, 25, 930. 37. High Temperature Propagation and Termination Kinetics of Styrene to High Conversion Investigated by Electron Paramagnetic Resonance Spectroscopy, P. B. Zetterlund, S. Yamauchi, B. Yamada, Macromol. Chem. Phys. 2004, 205, 778. 36. Addition-Fragmentation Chain Transfer: Molecular Weight Distributions and Retardation in the System Methyl Methacrylate/Methyl a-(bromomethyl)acrylate. P. B. Zetterlund, K. Miyake, K. Goto, B. Yamada, J. Polym. Sci.; Part A: Polym. Chem. 2004, 42, 2640. 35. Preparation of Macromonomers by Copolymerization of Methyl Acrylate Dimer Involving _-Fragmentation, T. Harada, P. B. Zetterlund, B. Yamada, J. Polym. Sci.; Part A: Polym. Chem. 2004, 42, 597. 34. Macromonomer Synthesis Using Oligomers of w-Unsaturated Methacrylate as Addition-Fragmentation Chain Transfer Agents: Increased Efficiency by Manipulation of Steric Hindrance. E. Sato, P. B. Zetterlund, B. Yamada, Macromolecules 2004, 37, 2363. 33. Influence of nitroxide structure on the 2,5- and 2,6-spirodicyclohexyl substituted cyclic nitroxide-mediated free-radical polymerization of styrene, F. Aldabbagh, P. Dervan, M. Phelan, K. Gilligan, D. Cunningham, P. McArdle, P. B. Zetterlund, B. Yamada, J. Polym. Sci.; Part A: Polym. Chem. 2003, 41, 3892. 32. Reactivities of omega-unsaturated methacrylate oligomers toward tert-butoxy radicals: Investigation of the effect of degree of polymerization and ester alkyl group, E. Sato, P. B. Zetterlund, B. Yamada, W. K. Busfield, I. D. Jenkins, Macromol. Chem. Phys. 2003, 204, 1882. 31. Effect of Mixing Sequence on the Properties of Carbon Black and Silica Filled Rubber, T. Kataoka, P. B. Zetterlund, B. Yamada, Plastics, Rubber and Composites 2003, 32, 291. 30. Free Radical Bulk Polymerization of Styrene: Simulation of Molecular Weight Distributions to High Conversion using Experimentally Obtained Rate Coefficients, P. B. Zetterlund, H. Yamazoe, B. Yamada, Macromol. Theory and Simul. 2003, 12, 379. 29. Macromonomer preparation by radical polymerization and copolymerization of the unsaturated tetramer of methyl acrylate, T. Hirano, P. B. Zetterlund, B. Yamada, Polymer J. 2003, 35, 491 28. Detailed studies of the initiation step in free radical polymerization of a-(substituted methyl)acrylates by electron paramagnetic resonance spectroscopy, E. Sato, P. B. Zetterlund, B. Yamada, Polymer 2003, 44, 2883. 27. Prevention of rubber degradation by use of microencapsulated antioxidants, T. Kataoka, P. B. Zetterlund, B. Yamada, Rubber Chem. Techn. 2003, 76, 948. 26. Effects of storage and service on tire performance: Oil component and swelling behavior, T. Kataoka, P. B. Zetterlund, B. Yamada, Rubber Chem. Techn. 2003, 76, 507. 25. Initiation in the free radical (co)polymerization of dialkyl fumarates and dicyclohexyl fumarate/tert-butyl vinyl ether investigated by a nitroxide trapping technique, E. Hirano, P. B Zetterlund, T. Takaoka, B. Yamada, R. Buckley, I. D. Jenkins, W K. Busfield, Polymer International 2003, 52, 1683. 24. Addition-fragmentation chain transfer involving dimers of a-methylvinyl monomers studied by electron spin resonance spectroscopy: Competition between fragmentation and bimolecular termination, P. B. Zetterlund, H. Yamazoe, B. Yamada, Macromolecular Rapid Communications, 2003, 24, 197. 23. Reaction behavior of sterically hindered -(substituted methyl)acrylic esters with tert-butoxy radicals studied by a nitroxide trapping technique, E. Sato, P. B. Zetterlund, B. Yamada, W. K. Busfield, I. D. Jenkins, Polymer International, 2003, 52, 1676 22. Propagation and termination in free radical polymerization of styrene to high conversion investigated by electron spin resonance spectroscopy, P. B. Zetterlund, H. Yamazoe, S. Yamauchi, B. Yamada, In: Advances in Controlled/Living Radical Polymerization, Matyjaszewski, K., Ed.; ACS Symposium Series 854, 2003, Chapter 6, pp. 72-85. 21. Early propagation kinetics in the free radical polymerization of methacrylonitrile investigated by a nitroxide trapping technique, K. Ewing, W. K. Busfield, I. D. Jenkins, P. B. Zetterlund, Polym. Int. 2003, 52, 1671. 20. Penultimate Unit Effects in Free Radical Copolymerization Studied Using the Individual Propagating Radical Concentrations from Electron Spin Resonance Spectroscopy, P. B. Zetterlund, S. Tagashira, K. Izumi, Y. Nagano, M. Azukizawa, H. Yamazoe, M. Kumagai, B. Yamada, Macromolecules 2002, 35, 8209. 19. Mechanisms and Kinetics of Imidazolidinone-Nitroxide Mediated Free Radical Polymerization of Styrene, P. Dervan, F. Aldabbagn, P. B. Zetterlund, B. Yamada, J. Polym. Sci.; Part A: Polym. Chem. 2003, 41, 327. 18. Propagation and termination kinetics in high conversion free radical copolymerization of styrene/divinylbenzene investigated by electron spin resonance and Fourier-transform near-infrared spectroscopy, P. B. Zetterlund, H. Yamazoe, B. Yamada, Polymer 2002, 43, 7027. 17. New Aspects of Unsaturated Polyester Resin Synthesis. Part II: Reactant Sequence Distribution and Its Effect on Cure Kinetics, P. B. Zetterlund, R. G. Gosden, W. Weaver and A. F. Johnson, Polym. Int. 2003, 52, 749. 16. Free Radical Polymerization of Styrene: Mass Spectrometric Identification of the First Fifteen Nitroxide-Trapped Oligomers and Estimated Propagation Rate Coefficients, P. B. Zetterlund, W. K. Busfield and I. D. Jenkins, Macromolecules 2002, 35, 7232. 15. Novel low temperature initiation systems for radical polymerization of methyl methacrylate, T. Takemoto, H. Shimonaka, E. Tokunaga, T. Tokimitsu, T.Makino, P. B. Zetterlund, B. Yamada, Polymer Preprints 2002, 43(2), 158. 14. Preparation of macromonomers at high temperature by copolymerizations involving acrylic and methacrylic esters, T. Harada, P. B. Zetterlund, B. Yamada, Polymer Preprints 2002, 43(2), 160. 13. Electron spin resonance investigations of propagation and termination in the free radical polymerization of styrene from zero to limiting conversion, P. B. Zetterlund, B. Yamada. Polymer Preprints 2002, 43(2), 142. 12. New Aspects of Unsaturated Polyester Resin Synthesis. Part I: Modelling and Simulation of Reactant Sequence Length Distributions in Stepwise Polymerization, P. B. Zetterlund, R. G. Gosden and A. F. Johnson, Polymer International 2003, 52, 104. 11. General Chemistry of Radical Polymerization, B. Yamada, P. B. Zetterlund in Handbook of Radical Polymerization, Eds. K. Matyjaszewski and T. P. Davis. Chapter 3. Wiley, 2002. 10. Free volume-based modelling of free radical crosslinking polymerisation of unsaturated polyesters, P. B. Zetterlund, A. F. Johnson, Polymer 2002, 43, 2039. 9. Kinetics of polyesterification: Modelling of the condensation of maleic anhydride, phthalic anhydride and 1,2-propylene glycol, P. B. Zetterlund, W. Weaver, A. F. Johnson. Polym. React. Eng. 2002, 10, 41. 8. High-conversion free-radical bulk polymerization of styrene: Termination kinetics studied by electron spin resonance, Fourier transform near-infrared spectroscopy, and gel permeation chromatography, P. B. Zetterlund, H. Yamazoe, B. Yamada, D. J. T. Hill, P. J. Pomery. Macromolecules 2001, 34, 7686. 7. Alkoxyamine-mediated "living" radical polymerization: MS investigation of the early stages of styrene polymerization initiated by cumyl-TEISO, S. P. Cresidio, F. Aldabbagh, W. K. Busfield, I. D. Jenkins, S. H. Thang, C. Zayas-Holdsworth, P. B. Zetterlund, J. Polym. Sci.; Part A: Polym. Chem. 2001, 39, 1232. 6. Free-radical bulk polymerization of styrene: ESR and near-infrared spectroscopic study of the entire conversion range, H. Yamazoe, P. B. Zetterlund, B. Yamada, D. J. T. Hill, P. J. Pomery, Macromol. Chem. Phys. 2001, 202, 824. 5. Free radical polymerization of acrylonitrile: mass spectrometric identification of the nitroxide-trapped oligomers formed in, and estimated rate constants for, each of the first ten propagation steps, P. B. Zetterlund, W. K. Busfield, I. D. Jenkins, Macromolecules 1999, 32, 8041. 4. Thermal and mechanical properties of polyurethanes derived from mono- and disaccharides, P. Zetterlund, S. Hirose, T. Hatakeyama, H. Hatakeyama, A-C. Albertsson. Polym. Int. 1997, 42, 1. 3. A new method for the determination of the Arrhenius constants for the cure process of unsaturated polyester resins based on a mechanistic model, P. B. Zetterlund, A. F. Johnson, Thermochimica Acta 1996, 289, 209. 2. TG-FTIR studies on biodegradable polyurethanes containing mono- and disaccharide components, K. Nakamura, Y. Nishimura, P. Zetterlund, T. Hatakeyama, H. Hatakeyama. Thermochimica Acta 1996, 283, 433. 1. Thermal and mechanical properties of polyurethanes from mono- and disaccharides, P. Zetterlund, S. Hirose, T. Hatakeyama, H. Hatakeyama. Reports on Progress in Polymer Physics in Japan 1995, 38, 533. |
| Activities for Academic Societies | The Society of Polymer Science, Japan American Chemical Society |